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potassium persulfate : ウィキペディア英語版
potassium persulfate

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:''Not to be confused with potassium peroxymonosulfate.''
Potassium persulfate is the inorganic compound with the formula K2S2O8. Also known as potassium peroxydisulfate or KPS, it is a white solid that is highly soluble in water. This salt is a powerful oxidant, commonly used to initiate polymerizations.
==Preparation==
Potassium persulfate can be prepared by electrolysis of a cold solution potassium bisulfate in sulfuric acid at a high current density.〔F. Feher, "Potassium Peroxydisulfate" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 392.〕
: 2 KHSO4 → K2S2O8 + H2
It can also be prepared by adding potassium bisulfate (KHSO4) to a solution of the more soluble salt ammonium peroxydisulfate (NH4)2S2O8. In principle it can be prepared by chemical oxidation of potassium sulfate using fluorine.

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